(E)-1-(2,2-Dimethoxyethyl)-2-(nitromethylidene)imidazolidine

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Benzoic acid–2-{(E)-[(E)-2-(2-pyridyl­methyl­idene)hydrazin-1-yl­idene]meth­yl}pyridine (2/1)

The asymmetric unit of the title cocrystal, C(12)H(10)N(4)·2C(7)H(6)O(2), comprises a single mol-ecule of benzoic acid and one half-mol-ecule of 2-pyridine-aldazine situated about a centre of inversion. The carboxyl group is coplanar with the benzene ring to which it is connected [O-C-C-C = -172.47 (12)°] and similarly, the 2-pyridine-aldazine mol-ecule is planar (r.m.s. deviation of the 16 non...

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2-Phenyl­acetic acid–(E,E)-4,4’-(hydra­zinediylidene)dipyridine (2/1)

The asymmetric unit of the title co-crystal, C(12)H(10)N(4)·2C(8)H(8)O(2), comprises a single mol-ecule of 2-phenyl-acetic acid and half a mol-ecule of 4-pyridine-aldazine as this is situated about a centre of inversion. Mol-ecules are connected into a three component aggregate via O-H⋯N hydrogen bonds. As the carb-oxy-lic acid group is almost normal to the plane through the benzene ring to whi...

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2-Phenyl­acetic acid–3-{(E)-2-[(E)-pyridin-3-yl­methyl­idene]hydrazin-1-ylidenemeth­yl}pyridine (2/1)

The asymmetric unit of the title 1:2 adduct, C(12)H(10)N(4)·2C(8)H(8)O(2), comprises a single mol-ecule of 2-phenyl-acetic acid and half a mol-ecule of 3-pyridine-aldazine; the latter is completed by crystallographic inversion symmetry. In the crystal, mol-ecules are connected into a three-component aggregate via O-H⋯N hydrogen bonds. As the carboxyl group lies above the plane through the benze...

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(E,E)-1-(2-Hydroxy­imino-1-phenyl­ethyl­idene)semicarbazide monohydrate

In the title compound, C(9)H(10)N(4)O(2)·H(2)O, the oxime unit has an E configuration, and an intra-molecular N-H⋯N hydrogen bond results in the formation of a planar five-membered ring, which is oriented with respect to the aromatic ring at a dihedral angle of 74.82 (17)°. In the crystal structure, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the mol-ecules and R(2) (2)(8) ring motifs a...

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2-(4-Chloro­phen­yl)acetic acid–2-{(E)-[(E)-2-(2-pyridyl­methyl­idene)hydrazin-1-yl­idene]meth­yl}pyridine (1/1)

In the crystal of the title 1:1 adduct, C(8)H(7)ClO(2)·C(12)H(10)N(4), the components are linked by an O-H⋯N hydrogen bond between the carb-oxy-lic acid and one of the pyridine N atoms. In the acid, the carb-oxy-lic acid group is approximately normal to [dihedral angle = 72.9 (2)°] but twisted with respect to the plane through the benzene ring [C-C-C-O torsion angle = 25.4 (5)°]. The base is ro...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810030266